There are a total of 55 Poké Ball and Master Ball Pokémon featured as usable items in Super Smash Bros. Ultimate. To see a compilation of all Poké Ball Pokémon in the recently released fighting game, click here. As you may already be aware, Master Balls will only contain Legendary Pokémon, Mythical Pokémon, Zoroark and Goldeen. Super Smash Bros. Ultimate is available now worldwide for Nintendo Switch.