James and Meowth don’t seem to be fazed by the fire coming out of Jessie’s mouth

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They're probably used to her overtly aggressive ways.

Flamethrower is apparently one of the Pokémon moves Jessie has at her disposal

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It's probably best not to make her angry.

If you make Jessie angry, she may very well start breathing fire at you

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She might also glare at you with her fiery eyes.